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Universal behaviour of silica suspensions gelled under shear
H J M Hanley1, C D Muzny, J Bartlett
1Australian Nuclear Science and Technology Organisation, PMB 1, Menai, NSW 2234, Australia. Australian National University, Canberra, ACT 0200, Australia.
Abstract:
The shear-influenced gelation of three aqueous suspensions consisting of silica particles of nominal diameter 7, 12 and 24 nm, respectively, is reported. It is shown that the viscosity/stress of a gelling system increases with time after gel initiation, reaches a maximum, then falls to a plateau value. A very simple relation between this maximum stress and the precursor volume fraction is verified experimentally.
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