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Experimental and Theoretical Aspects of Anion Complexes with a Thiophene-Based Cryptand
Syed A Haque1, Musabbir A Saeed1, Afsana Jahan1
1Department of Chemistry and Biochemistry, Jackson State University, Jackson, MS 39217.
Abstract:
Selective recognition of anions has received a tremendous attention in recent years because of their significant importance in biology and environment. This article highlights our recent research on a thiophene-based azacryptand that has been shown to effectively bind anions including iodide, bromide, chloride, nitrate and sulfate. Structural studies indicate that the ligand forms inclusion complexes with chloride and iodide. On the other hand, it forms cleft-like complexes with nitrate and sulfate, where three anions are bound between the cyclic arms. The ligand binds each anion with a 1:1 binding mode in water, exhibiting strong selectivity for sulfate; which is further supported by ESI-MS and DFT calculations.
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