Cross-Dehydrogenative C-H Amination of Indoles under Aerobic Photo-oxidative Conditions
Tomoaki Yamaguchi1, Eiji Yamaguchi1, Akichika Itoh1
1Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan.
Abstract:
A novel cross-dehydrogenative C(sp2)-H amination catalyzed by an organic photocatalyst is reported. The reaction is mediated by 2-tert-butylanthraquinone as a photocatalyst, harmless visible light, and aerobic oxygen as the sole oxidant without a transition-metal catalyst and or external oxidant.
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