P2- and P3-KxCoO2 as an electrochemical potassium intercalation host
Yuya Hironaka1, Kei Kubota2, Shinichi Komaba2
1Department of Applied Chemistry, Tokyo University of Science, Shinjuku, Tokyo 162-8601, Japan. komaba@rs.kagu.tus.ac.jp.
Abstract:
Reversible and topotactic potassium intercalation of P2- and P3-KxCoO2 electrodes is studied in non-aqueous K cells for the first time. They deliver a highly reversible capacity of 60 mA h g-1 in the voltage range 2.0-3.9 V accompanied by reversible phase transitions including potassium/vacancy orderings. The electrochemical properties and structural change of P2-KxCoO2 are compared to those of O2-LixCoO2 and P2-NaxCoO2.
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