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Dynamic Phosphorescent Probe for Facile and Reversible Stress Sensing.

Georgy A Filonenko1, Julia R Khusnutdinova1

  • 1Coordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa, 904-0495, Japan.

Advanced Materials (Deerfield Beach, Fla.)
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A novel dynamic phosphorescent copper complex in polyurethanes offers a reversible stress sensor. This material shows stress-specific photoluminescence changes, enabling optical mapping of stress in polymers.

Keywords:
luminescencemacrocyclic ligandsmechanical propertiespolymerssensors

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Photophysics

Background:

  • Deformation sensors commonly rely on bond scission or structural changes.
  • Existing sensors may lack specificity or reversibility under stress.

Purpose of the Study:

  • To develop a facile and reversible stress sensor based on dynamic phosphorescence.
  • To investigate the mechanism of stress response in metalated polymers.

Main Methods:

  • Incorporation of a dynamic phosphorescent copper complex into polyurethane main chains.
  • Tensile stress application (5-35 MPa) to metalated polymers and blends.
  • Monitoring photoluminescence intensity changes using optical imaging.

Main Results:

  • The dynamic phosphorescent copper complex exhibits a reversible response to tensile stress without bond scission.
  • Stress-induced suppression of nonradiative relaxation pathways governs the photoluminescence response.
  • A nearly twofold increase in photoluminescence intensity was observed under 5-35 MPa stress.
  • The sensor demonstrated stress specificity.

Conclusions:

  • Dynamic phosphorescent polyurethanes serve as effective stress sensors.
  • The sensor allows for optical mapping of stress distribution and tracking of dynamic phenomena in polymers.