Synthesis and Optoelectronic Properties of Hexa-peri-hexabenzoborazinocoronene
Jacopo Dosso1, Jonathan Tasseroul2, Francesco Fasano1
1School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Abstract:
The first rational synthesis of a BN-doped coronene derivative in which the central benzene ring has been replaced by a borazine core is described. This includes six C-C ring-closure steps that, through intramolecular Friedel-Crafts-type reactions, allow the stepwise planarization of the hexaarylborazine precursor. UV/Vis absorption, emission, and electrochemical investigations show that the introduction of the central BN core induces a dramatic widening of the HOMO-LUMO gap and an enhancement of the blue-shifted emissive properties with respect to its all-carbon congener.
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