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Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model
Published on: August 22, 2015
Structural and vibrational properties of corundum-type In2O3 nanocrystals under compression
J A Sans1, R Vilaplana2, D Errandonea3
1Instituto de Diseño para la Fabricación y Producción Automatizada, MALTA Consolider Team-Universitat Politècnica de València, E-46022 València, Spain.
Nanocrystalline indium(III) oxide (In2O3) exhibits enhanced structural stability under high pressure compared to its bulk form. This study investigates its properties up to 30 GPa using X-ray diffraction and Raman spectroscopy.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Corundum-type indium(III) oxide (rh-In2O3) is a material with significant technological applications.
- Understanding its behavior under high pressure is crucial for its use in extreme environments.
- Previous studies on bulk rh-In2O3 indicate a phase transition at elevated pressures.
Purpose of the Study:
- To investigate the structural and vibrational properties of nanocrystalline rh-In2O3 under high pressure.
- To compare the stability of nanocrystalline rh-In2O3 with its bulk counterpart.
- To elucidate the effects of nanostructuring on the high-pressure behavior of rh-In2O3.
Main Methods:
- Angle-dispersive X-ray diffraction (XRD) up to 30 GPa.
- Raman scattering measurements up to 30 GPa.
- Analysis of the equation of state and pressure-dependent vibrational modes.
Main Results:
- The equation of state for nanocrystalline rh-In2O3 aligns with theoretical predictions and bulk experimental data.
- Raman-active modes show pressure dependence consistent with bulk material.
- Nanocrystalline rh-In2O3 demonstrates stability up to at least 20 GPa, exceeding the stability of bulk rh-In2O3.
Conclusions:
- Nanostructuring significantly enhances the pressure stability of corundum-type In2O3.
- The observed enhanced stability in nanocrystalline rh-In2O3 is attributed to unique nanoscale effects.
- This finding has implications for the design and application of In2O3-based materials in high-pressure environments.
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