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Photoelectrochemical dimethoxylation of furan via a bromide redox mediator using a BiVO4/WO3 photoanode
1Advanced Functional Materials Team, Research Center for Photovoltaics (RCPV), National Institute of Advanced Industrial Science and Technology (AIST), Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. k.sayama@aist.go.jp.
Abstract:
Photoelectrochemical dimethoxylation of furan with methanol using a BiVO4/WO3 photoanode and Br+/Br- as a mediator was demonstrated with low applied potential. The faradaic efficiency for the dimethoxylation with a Et4NBF4 co-supporting electrolyte at +0.1 V vs. SHE was almost quantitative up to 99%.
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