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Effect of the reaction medium on the immobilization of nutrients in hydrochars obtained using sugarcane industry
Camila Centurion Silva1, Camila Almeida Melo1, Francisco Holanda Soares Junior2
1Instituto de Biociências, Letras e Ciências Exatas, UNESP, Univ Estadual Paulista, Campus São José do Rio Preto, Departamento de Química e Ciências Ambientais, Laboratório de Estudos em Ciências Ambientais, Cristóvão Colombo, 2265, São José do Rio Preto, São Paulo State 15054-000, Brazil.
Abstract:
In this study, nutrients were immobilized on the hydrochars obtained by hydrothermal carbonization (HTC) of a vinasse and sugarcane bagasse mixture, in the presence of acid, base and salt additives at temperatures of 150, 190 and 230°C. The increase in temperature caused higher immobilization of Ca, Mg, K, N, Cu, Mn, Zn, B, P and Fe in all hydrochars produced. H3PO4 and NaOH immobilized higher amounts of P, Mg and Mn, while Ca was immobilized in higher quantities in the presence of H3PO4 and (NH4)2SO4. The addition of H2SO4, H3PO4 and (NH4)2SO4 was responsible for an increased immobilization of P, N, Ca, Mg and K. The immobilization of B, not present in the starting raw material, was possible with the addition of H3BO3. The results showed that it is possible to alter the reaction medium to immobilize nutrients on hydrochars produced from vinasse and sugarcane bagasse, for agricultural applications.
