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The temperature-composition phase diagram of two solids, A and B, which are immiscible in the solid phase but form miscible liquids, shows that when the temperature is low, these two exist as separate, pure solids (A and B). As the temperature increases, they transition into a single-phase liquid solution where A and B coexist. Moving from point a1 to a2 in the phase diagram, the composition changes such that solid B begins to separate from the solution, enriching the remaining liquid with A.
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A pressure-composition phase diagram explicitly describes the behavior of an ideal solution of two volatile liquids under varying pressures and compositions. A pressure-composition diagram has two main curves. The bubble point curve represents the plot of pressure versus liquid mole fraction. It indicates the pressure at which the first bubble of vapor forms from the liquid phase as the system pressure decreases.The dew point curve is the pressure versus vapor mole fraction. It indicates the...
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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
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The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...
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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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Pressure-induced structural change in liquid GaIn eutectic alloy.

Q Yu1, A S Ahmad1, K Ståhl2

  • 1International Center for New-Structured Materials and Laboratory of New-Structured Materials, State Key Laboratory of Silicon Materials & School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.

Scientific Reports
|April 27, 2017
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Summary
This summary is machine-generated.

High pressure transforms liquid Gallium-Indium (GaIn) eutectic alloy into a crystalline phase. This transformation is reversible upon pressure release, offering insights into atomic-level phase transitions.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Physical Chemistry

Background:

  • Understanding the behavior of eutectic alloys under extreme conditions is crucial for materials science.
  • Gallium-Indium (GaIn) alloys are technologically relevant, necessitating studies on their phase transitions.

Purpose of the Study:

  • To investigate the pressure-induced phase transformations of a liquid GaIn eutectic alloy.
  • To elucidate the atomic-level mechanisms governing liquid-to-crystalline transitions under pressure.

Main Methods:

  • Synchrotron X-ray diffraction was employed to observe structural changes.
  • High-pressure experiments were conducted using a diamond anvil cell at room temperature.
  • Ab initio molecular dynamics calculations were performed for theoretical analysis.

Main Results:

  • A pressure-induced crystallization occurred at approximately 3.4 GPa.
  • A polymorphic transition was observed near 10.3 GPa.
  • The crystalline phase reverted to liquid around 2.3 GPa upon decompression.
  • Calculations revealed non-uniform contraction and changes in local atomic packing.

Conclusions:

  • Pressure induces reversible crystallization and polymorphic transitions in liquid GaIn eutectic alloy.
  • The liquid-crystalline phase transformation is driven by alterations in nearest-neighbor atomic packing and electronic structures.