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Updated: Mar 3, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Olefin Cross-Metathesis in Polymer and Polysaccharide Chemistry: A Review
Yifan Dong1, John B Matson1, Kevin J Edgar1
1Department of Sustainable Biomaterials, ‡Department of Chemistry, and §Macromolecules Innovation Institute, Virginia Tech , Blacksburg, Virginia 24061, United States.
Abstract:
Olefin cross-metathesis, a ruthenium-catalyzed carbon-carbon double bond transformation that features high selectivity, reactivity, and tolerance of various functional groups, has been extensively applied in organic synthesis and polymer chemistry. Herein, we review strategies for performing selective cross-metathesis and its applications in polymer and polysaccharide chemistry, including constructing complex polymer architectures, attaching pendant groups to polymer backbones and surfaces, and modifying polysaccharide derivatives.
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