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Monitoring the Effects of Illumination on the Structure of Conjugated Polymer Gels Using Neutron Scattering
Published on: December 21, 2017
Solvatochromism as a probe to observe the solvent exchange process in a 1-D porous coordination polymer with 1-D
Charl X Bezuidenhout1, Catharine Esterhuysen, Leonard J Barbour
1Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland, 7602, South Africa. ljb@sun.ac.za.
Abstract:
A one-dimensional porous coordination polymer (PCP) {[Cu2(acetate)2(3,6-di(pyridin-4-yl)-1,2,4,5-tetrazine)]·2CHCl3}n possesses pleochroic properties. Solvent exchange with acetonitrile and nitromethane reveals that single crystals of the PCP are also solvatochromic, with the solvent exchange process occurring in an unexpected double V-shaped pattern. Crystal surface adsorption modeling shows that the origin of this effect is preferential sorption at two faces of the crystal.
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