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Updated: Mar 2, 2026

Fabrication of Large-area Free-standing Ultrathin Polymer Films
Published on: June 3, 2015
Strong van der Waals Adhesion of a Polymer Film on Rough Substrates
Juliane Klatt1, Pablo Barcellona1, Robert Bennett1
1Physikalisches Institut, Albert-Ludwigs-Universität Freiburg , Hermann-Herder-Str. 3, 79104 Freiburg, Germany.
Abstract:
We propose that chemically inert polymeric films can enhance van der Waals (vdW) forces in the same way as nanofabrication of biomimetic adhesive materials. For the vdW adhesion of an ethylene-chlorotrifluoroethylene (ECTFE) film on rough metal and dielectric substrates, we present a model that combines microscopic quantum-chemistry simulations of the polymer response functions and the equilibrium monomer-substrate distance with a macroscopic quantum-electrodynamics calculation of the Casimir force between the polymer film and the substrate. We predict adhesive forces up to 2.22 kN/mm2, where the effect is reduced by substrate roughness and for dielectric surfaces.
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