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Preparation of Alkynes: Alkylation Reaction02:27

Preparation of Alkynes: Alkylation Reaction

12.5K
Introduction
Alkylation of terminal alkynes with primary alkyl halides in the presence of a strong base like sodium amide is one of the common methods for the synthesis of longer carbon-chain alkynes. For example, treatment of 1-propyne with sodium amide followed by reaction with ethyl bromide yields 2-pentyne.
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Structure and Physical Properties of Alkynes02:37

Structure and Physical Properties of Alkynes

14.2K
Introduction:
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
The...
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

9.2K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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Electrophilic Aromatic Substitution: Friedel–Crafts Acylation of Benzene01:11

Electrophilic Aromatic Substitution: Friedel–Crafts Acylation of Benzene

9.4K
The Friedel–Crafts acylation reactions involve the addition of an acyl group to an aromatic ring. These reactions proceed via electrophilic aromatic substitution by employing an acyl chloride and a Lewis acid catalyst such as aluminum chloride to form aryl ketone.
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Free-Radical Chain Reaction and Polymerization of Alkenes02:35

Free-Radical Chain Reaction and Polymerization of Alkenes

10.0K
The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
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Cycloaddition Reactions: MO Requirements for Photochemical Activation01:12

Cycloaddition Reactions: MO Requirements for Photochemical Activation

2.8K
Some cycloaddition reactions are activated by heat, while others are initiated by light. For example, a [2 + 2] cycloaddition between two ethylene molecules occurs only in the presence of light. It is photochemically allowed but thermally forbidden.
2.8K

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Related Experiment Video

Updated: Mar 2, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

8.0K

Initiation Reactions in Acetylene Pyrolysis.

Judit Zádor1, Madison D Fellows1, James A Miller2

  • 1Combustion Research Facility, Mail Stop 9055, Sandia National Laboratories , Livermore, California 94551-0969, United States.

The Journal of Physical Chemistry. A
|May 11, 2017
PubMed
Summary
This summary is machine-generated.

Acetylene

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Area of Science:

  • Combustion Chemistry
  • Chemical Kinetics

Background:

  • Acetylene's role in molecular weight growth in combustion is significant.
  • Current understanding of acetylene pyrolysis initiation below 1500 K is incomplete, with debated mechanisms.
  • Existing theories lack rigorous theoretical or experimental validation for low-temperature initiation.

Purpose of the Study:

  • To investigate the low-temperature initiation mechanisms of acetylene pyrolysis.
  • To calculate pressure- and temperature-dependent rate coefficients for acetylene association reactions.
  • To elucidate the role of vinylidene in acetylene self-reaction.

Main Methods:

  • Utilized ab initio transition-state theory master equation methods.
  • Calculated pressure- and temperature-dependent rate coefficients.
  • Analyzed isomerization dynamics and compared theoretical results with experimental data.

Main Results:

  • Established the significant role of vinylidene, a high-energy acetylene isomer, in the initiation process.
  • Quantified rate coefficients for acetylene association and related reactions.
  • Demonstrated the competition between first-order and second-order initiation steps.

Conclusions:

  • The study provides rigorous theoretical evidence for acetylene self-reaction initiation via vinylidene below 1500 K.
  • Highlights the importance of isomerization dynamics in combustion models.
  • Emphasizes the need for time-scale analysis when comparing theoretical rates with experimental observations.