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A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates
Zhen-Wen Cai1, Tao Yang, Yan-Jie Qi
1State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China. stzheng@fzu.edu.cn.
Dalton Transactions (Cambridge, England : 2003)
|May 16, 2017
Abstract:
We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb6Sc11W60}, {Sb8Sc7W60}, and {Sb8Sc6W60}. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc3+ ions of any polyoxotungstates reported to date.

