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The tailored synthesis of nanosized SAPO-34 via time-controlled silicon release enabled by an organosilane precursor
Jingwei Zheng1, Jiajia Ding, Dongliang Jin
1State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China. xgzhou@ecust.edu.cn.
Chemical Communications (Cambridge, England)
|May 23, 2017
Abstract:
Phenyltrimethoxysilane as a Si source can significantly slow down the crystallization process for SAPO-34 synthesis, leading to the formation of agglomerated nanocrystals (<100 nm). The obtained nanosized SAPO-34 shows enhanced catalytic stability in methanol-to-olefin conversion under industrially relevant conditions.
