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Updated: Mar 2, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule
K Kizaki1, H Ozawa, T Kobayashi
1Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyamacho, Toyonaka, Osaka 560-0043, Japan. iskw@chem.sci.osaka-u.ac.jp.
Abstract:
A new type of electronic interaction which couples two angular momenta, i.e. the angular momentum of a localized 4f system (J) and an orbital angular momentum generated in a cyclic π conjugated system by irradiation with a circularly-polarized light, has been identified in a lanthanide single molecule magnet.
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