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Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
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Photochemical Hexadehydro-Diels-Alder Reaction

Feng Xu1, Xiao Xiao1, Thomas R Hoye1

  • 1Department of Chemistry, University of Minnesota , 207 Pleasant Street, SE, Minneapolis, Minnesota 55455, United States.

Journal of the American Chemical Society
|May 27, 2017
PubMed
Summary

Photochemical initiation of the hexadehydro-Diels-Alder (HDDA) reaction offers a new method for generating benzyne derivatives. This photo-HDDA process works at low temperatures without traditional reagents, producing benzynes identical to those from thermal methods.

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