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"Turn-on" Fluorescence Sensing and Discriminative Detection of Aliphatic Amines Using a 5-Fold-Interpenetrated
Prabu Mani1, Anupam Anand Ojha1, Vennapusa Sivaranjana Reddy1
1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram ,Thiruvananthapuram, Kerala, India 695016.
Inorganic Chemistry
|May 31, 2017
Abstract:
A 5-fold-interpenetrated zinc-based coordination polymer can discriminately detect aliphatic amines through a fluorescence "turn-on" method. This compound can sense aliphatic amines in the solid state, solution state, and vapor phase. Theoretical calculations revealed that the ground-state dipole moment of the corresponding amines guides the order of enhancement.

