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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
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Theoretical study on stabilization mechanisms of nitrate esters using aromatic amines as stabilizers

Zhi-Dan Sun1, Xiao-Long Fu2, Hong-Jian Yu2

  • 1Key Laboratory of Soft Chemistry and Functional Materials of MOE, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China.

Journal of Hazardous Materials
|July 4, 2017
PubMed
Summary

Aromatic amines stabilize nitrate ester propellants by reacting with nitro dioxide (NO2). This reaction has lower activation energy, preventing NO2 from catalyzing propellant decomposition.

Keywords:
Catalysis of NO(2)Density functional theoryNitrate estersReaction mechanismStabilizers of aromatic amines

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