Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions

Organic-inorganic halide perovskite materials (e.g., MAPbI₃, FAPbI₃, etc.; where MA = CH₃NH₃⁺, FA = CH(NH₂)₂⁺) have been studied intensively for photovoltaic applications. Major concerns for the commercialization of perovskite photovoltaic technology to take off include lead toxicity, long-term stability, hysteresis, and optimal bandgap. Therefore, there is still need for further exploration of alternative candidates. Elemental composition engineering of MAPbI₃ and FAPbI₃ has been proposed to address the above concerns. Among the best six certified power conversion efficiencies reported by National Renewable Energy Laboratory on perovskite-based solar cells, five are based on mixed perovskites (e.g., MAPbI_1-xBr_x, FA_0.85MA_0.15PbI_2.55Br_0.45, Cs_0.1FA_0.75MA_0.15PbI_2.49Br_0.51). In this paper, we review the recent progress on the synthesis and fundamental aspects of mixed cation and halide perovskites correlating with device performance, long-term stability, and hysteresis. In the outlook, we outline the future research directions based on the reported results as well as related topics that warrant further investigation.