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Updated: Feb 27, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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A silver(i)-induced higher-ordered structure based on planar chiral tetrasubstituted [2.2]paracyclophane

Masayuki Gon1, Yasuhiro Morisaki, Yoshiki Chujo

  • 1Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. chujo@chujo.synchem.kyoto-u.ac.jp.

Chemical Communications (Cambridge, England)
|July 8, 2017
PubMed
Summary

Optically active phenylene-ethynylene dimers were synthesized using chiral paracyclophane. Pyridine-silver coordination controlled conformation, enhancing circular dichroism signals while reducing circularly polarized luminescence.

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