Tuning Plasmon Resonance in Magnetoplasmonic Nanochains by Controlling Polarization and Interparticle Distance for...

Magnetoplasmonic Fe₃O₄-coated Ag nanoparticles (NPs) are assembled in large scale (18 × 18 mm²) in order to observe unique modulation of plasmonic coupling and optical tunable application via both external magnetic field and the combination of magnetic dipole and electrostatic interactions of particle-particle and particle-substrate. These large nanochains film exhibits outstanding tunability of plasmonic resonance from visible to near-infrared range by controlling the polarization angle and interparticle distance (IPD). The enormous spectral shift mainly originated from far-field rather than near-field coupling of Ag cores because of the sufficiently large separation between them in which Fe₃O₄ shell acts as spacer. This tunable magnetoplasmonic film can be applicable in the field of anisotropic optical waveguides, tunable optical filter, and nanoscale sensing platform.