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Updated: Feb 25, 2026

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

Published on: June 13, 2022

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N-Methyl Inversion and Accurate Equilibrium Structures in Alkaloids: Pseudopelletierine

Montserrat Vallejo-López1, Patricia Écija1, Natalja Vogt2

  • 1Departamento de Química Física, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apartado 644, 48080, Bilbao, Spain.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|August 1, 2017
PubMed
Summary

Rotational spectroscopy revealed two distinct conformers of the alkaloid pseudopelletierine in the gas phase. The study determined their structural properties and conformational equilibrium, favoring the axial form.

Keywords:
ab initio calculationsalkaloidsconformational analysisrotational spectroscopystructure elucidation

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