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Gyan H Aryal1, Khaleel I Assaf, Kenneth W Hunter

  • 1A Department of Microbiology and Immunology, School of Medicine, University of Nevada, Reno, NV 89557, USA. huang@med.unr.edu.

Chemical Communications (Cambridge, England)
|August 3, 2017
PubMed

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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