Corrosion Inhibition of High Speed Steel by Biopolymer HPMC Derivatives
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Published on: December 26, 2016
Shih-Chen Shi1, Chieh-Chang Su2
1Department of Mechanical Engineering, National Cheng Kung University (NCKU), No. 1 University Road, Tainan 70101, Taiwan. scshi@mail.ncku.edu.tw.
Abstract:
The corrosion inhibition characteristics of the derivatives of biopolymer hydroxypropyl methylcellulose (HPMC), hydroxypropyl methylcellulose phthalate (HPMCP), and hydroxypropyl methylcellulose acetate succinate (HPMCAS) film are investigated. Based on electrochemical impedance spectroscopic measurements and potentiodynamic polarization, the corrosion inhibition performance of high speed steel coated with HPMC derivatives is evaluated. The Nyquist plot and Tafel polarization demonstrate promising anti-corrosion performance of HPMC and HPMCP. With increasing film thickness, both materials reveal improvement in corrosion inhibition. Moreover, because of a hydrophobic surface and lower moisture content, HPMCP shows better anti-corrosion performance than HPMCAS. The study is of certain importance for designing green corrosion inhibitors of high speed steel surfaces by the use of biopolymer derivatives.
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