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Crystal structure and Hirshfeld surface analysis of (E)-4-amino-N'-[1-(4-methyl-phen-yl)ethyl-idene]benzohydrazide
Palaniyappan Sivajeyanthi1, Muthaiah Jeevaraj1, Bellarmin Edison1
1Department of Chemistry, Government Arts College (Autonomous), Thanthonimalai, Karur 639 005, Tamil Nadu, India.
Abstract:
The structure of the title Schiff base, C16H17N3O, displays a trans configuration with respect to the C=N double bond, with a dihedral angle of 14.98 (9)° between the benzene rings. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen-bonding inter-actions, giving sheets extending across the (001) plane. Hirshfeld surface analysis gave fingerprint plots showing enrichment ratios for H⋯H, O⋯H, N⋯H and C⋯H contacts compared to C⋯C, N⋯N and C⋯N contacts, indicating a high propensity for H⋯H interactions to form in the crystal.
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