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Qualitative Identification of Carboxylic Acids, Boronic Acids, and Amines Using Cruciform Fluorophores
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Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability.

Meiko Kawai1, Ayaka Hoshi, Ryuhei Nishiyabu

  • 1Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan. yujik@tmu.ac.jp.

Chemical Communications (Cambridge, England)
|August 30, 2017
PubMed
Summary

Chiral ensembles spontaneously formed using di(boronic acid)-appended tetraphenylethylene (DB-TPE) and tartaric acid. These ensembles enable enantioselective aggregation and fluorescent recognition of chiral molecules like diamines and cinchona alkaloids.

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