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Updated: Feb 23, 2026

07:45
Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
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A highly crystalline oriented metal-organic framework thin film with an inorganic pillar
Yuki Watanabe1, Tomoyuki Haraguchi, Kazuya Otsubo
1Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto, 606-8502, Japan. kazuya@kuchem.kyoto-u.ac.jp kitagawa@kuchem.kyoto-u.ac.jp.
Abstract:
We report a step-by-step route to fabricate the first example of a crystalline oriented metal-organic framework thin film having an anionic inorganic pillar ligand, {Cu(4,4'-bipyridyl)2(SiF6)}. X-ray study and sorption analysis revealed its high crystallinity and porous character.

