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Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
Published on: April 17, 2018
A 5-μm pitch charge-coupled device optimized for resonant inelastic soft X-ray scattering
N C Andresen1, P Denes1, A Goldschmidt1
1Lawrence Berkeley National Laboratory (LBNL), 1 Cyclotron Road, Berkeley, California 94720, USA.
We developed a new charge-coupled device (CCD) optimized for Resonant Inelastic X-ray Scattering (RIXS). This high-efficiency X-ray detector offers improved spectroscopic performance for advanced research applications.
Area of Science:
- X-ray instrumentation
- Detector physics
- Materials science
Background:
- Advancements in X-ray spectroscopy require detectors with high efficiency and resolution.
- Existing charge-coupled devices (CCDs) may have limitations in specific applications like Resonant Inelastic X-ray Scattering (RIXS).
Purpose of the Study:
- To develop and characterize a novel CCD optimized for RIXS.
- To evaluate the performance of the new CCD compared to existing technologies.
Main Methods:
- Fabrication of a fully depleted, back-illuminated CCD with 5 μm × 45 μm pixels on high-resistivity silicon.
- Testing the CCD at the Advanced Light Source (ALS) RIXS beamline.
- Performance evaluation using a C K-edge X-ray beam on a graphite sample.
Main Results:
- The 1.5-megapixel CCD demonstrates high efficiency for soft to hard X-rays (>8 keV).
- Achieved quantum efficiency >75% from 200 eV to 1 keV.
- Readout noise of 3-6 electrons and a point spread function of 4.0 μm ± 0.2 μm for soft X-rays.
Conclusions:
- The developed CCD offers superior spectroscopic performance for RIXS, especially for spectrometers with limited arm lengths.
- The detector's design and performance represent a significant improvement over current commercial cameras for specific X-ray applications.
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