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Related Concept Videos

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
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Updated: Feb 23, 2026

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Nanogels as a Basis for Network Construction.

Eric Dailing1, JianCheng Liu1, Steven Lewis2

  • 1Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309, USA.

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|September 5, 2017
PubMed
Summary
This summary is machine-generated.

Reactive nanogels improve dental resins by reducing shrinkage and stress while enhancing bond strength. These advanced fillers create unique macroscopic networks, expanding material possibilities.

Keywords:
mechanical propertiesnanogelsshrinkage stress

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Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Biomaterials Engineering

Background:

  • Conventional monomer resins often suffer from polymerization shrinkage and stress, potentially compromising material integrity and clinical performance.
  • Developing advanced filler materials is crucial for enhancing the properties of polymer-based composites, such as dental restorative materials.

Purpose of the Study:

  • To synthesize reactive nanogels with tailored chemical and physical properties.
  • To investigate the effects of incorporating these nanogels as fillers in conventional monomer resins.
  • To explore the formation of macroscopic networks with novel compositions using nanogels.

Main Methods:

  • Solution free radical polymerization was employed for the synthesis of reactive nanogels.
  • Nanogels were incorporated as fillers into conventional monomer resins.
  • The resulting macroscopic networks formed by nanogels in inert solvents were characterized.

Main Results:

  • Nanogel fillers significantly reduced polymerization shrinkage and stress in monomer resins.
  • Improved bond strength was observed when nanogels were utilized as fillers.
  • Macroscopic networks with unique chemical compositions, not achievable from monomers alone, were formed by dispersed nanogels.

Conclusions:

  • Reactive nanogels are effective fillers for improving the performance of monomer resins, particularly in applications requiring reduced shrinkage and stress.
  • The use of nanogels offers a pathway to create advanced composite materials with enhanced mechanical properties and novel compositions.
  • This approach holds promise for developing next-generation biomaterials and dental restorative systems.