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(Metallo)porphyrins for potential materials science applications.

Lars Smykalla1, Carola Mende2, Michael Fronk3

  • 1Solid Surfaces Analysis Group, Institute of Physics, Faculty of Natural Sciences, TU Chemnitz, D-09107 Chemnitz, Germany.

Beilstein Journal of Nanotechnology
|September 15, 2017
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Molecular-based systems offer miniaturized devices with advanced functionalities through tailored molecule self-assembly. This review explores metalloporphyrins for fabricating novel molecular devices with unforeseeable applications in materials science.

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atomic force microscopymagneto-optical Kerr effect spectroscopyscanning tunnelling microscopy and spectroscopyself-assemblysurface-confined 2D polymerizationtransport properties

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Molecular Engineering

Background:

  • The pursuit of miniaturized electronic devices drives interest in bottom-up, molecular-based fabrication.
  • Molecular systems offer enhanced functionalities and potential for novel device architectures.

Purpose of the Study:

  • To review the use of discrete (metallo)porphyrins in constructing molecular-based systems.
  • To discuss fabrication methods and properties of these molecular ensembles.
  • To explore their application potential in materials science.

Main Methods:

  • Surface-confined polymerization for (sub)monolayer formation.
  • Supramolecular recognition for monolayer assembly.
  • Sublimation techniques for thin film deposition.

Main Results:

  • (Metallo)porphyrins can form ordered structures including (sub)monolayers and thin films.
  • Fabrication methods enable control over molecular arrangement and device architecture.
  • Selected physical properties of the resulting molecular systems are presented.

Conclusions:

  • Discrete (metallo)porphyrins are versatile building blocks for molecular devices.
  • Tailored self-assembly and fabrication techniques unlock significant application potential.
  • Further exploration of these molecular ensembles is crucial for advancing materials science.