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Updated: Feb 22, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Oxygenation of RZn(N,O)-type complexes as an efficient route to zinc alkoxides not accessible via the classical
Zbigniew Wróbel1, Tomasz Pietrzak2, Iwona Justyniak1
1Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw 01-224, Poland.
Abstract:
The controlled oxygenation of alkylzinc complexes supported by a 2-ester substituted pyrrolate ligand (L) leads to zinc alkoxides with an uncommon structural motif in the solid state: a trimer [(L)Zn(μ-OtBu)]3 with the central [Zn3(μ-OR)3] ring and a tetramer [(L)Zn(μ3-OEt)]4 with a heterocubane-type structure. Strikingly, these seemingly simple zinc alkoxides are not accessible via the classical alcoholysis route.
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