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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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C(sp3 )-H Bond Activation by Vinylidene Gold(I) Complexes: A Concerted Asynchronous or Stepwise Process?

Johannes E M N Klein1,2, Gerald Knizia3, Laura Nunes Dos Santos Comprido4

  • 1Department of Chemistry, University of Minnesota, 207 Pleasant St SE, Minneapolis, MN, 55455, USA.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|September 19, 2017
PubMed

Keywords:
C−H activationbond orbital analysiscomputational chemistrygold(I)reaction mechanisms

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