Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

31.1K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
31.1K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

48.9K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
48.9K
X-ray Crystallography02:18

X-ray Crystallography

26.4K
The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
26.4K
Crystal Growth: Principles of Crystallization01:25

Crystal Growth: Principles of Crystallization

5.3K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
5.3K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Is a data deluge dampening our idea generation capability?

Innovation (Cambridge (Mass.))·2025
Same author

Heterosynthons, Solid Form Design and Enhanced Drug Bioavailability.

Angewandte Chemie (International ed. in English)·2022
Same author

Crystal engineering in <b>IUCrJ</b> 2021: interactions, structures, properties.

IUCrJ·2022
Same author

Reply to the 'Comment on "Trimorphs of 4-bromophenyl 4-bromobenzoate. Elastic, brittle, plastic"' by J. J. Whittaker, A. J. Brock, A. Grosjean, M. C. Pfrunder, J. C. McMurtrie and J. K. Clegg, <i>Chem. Commun.</i>, 2021, <b>57</b>, DOI: 10.1039/D0CC07668F.

Chemical communications (Cambridge, England)·2021
Same author

Synthetic Approaches to Halogen Bonded Ternary Cocrystals.

Angewandte Chemie (International ed. in English)·2021
Same author

Crystal engineering in IUCrJ: from 'the' crystal structure to 'a' crystal structure.

IUCrJ·2021

Related Experiment Video

Updated: Feb 21, 2026

Microcrystallography of Protein Crystals and In Cellulo Diffraction
09:35

Microcrystallography of Protein Crystals and In Cellulo Diffraction

Published on: July 21, 2017

9.6K

Approaches to crystal structure landscape exploration.

Gautam R Desiraju1

  • 1Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India.

Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials
|October 6, 2017
PubMed
Summary

Exploring the crystal structure landscape is crucial. This study outlines three key methods: crystal structure prediction, non-ambient crystallography, and charge density analysis for deeper material insights.

Keywords:
charge density analysiscrystal engineeringcrystal structure landscapecrystal structure predictionnon-ambient crystallography

More Related Videos

Author Spotlight: Advancing Protein Structure Analysis for Drug Development
07:08

Author Spotlight: Advancing Protein Structure Analysis for Drug Development

Published on: March 8, 2024

4.4K
Sample Preparation and Transfer Protocol for In-Vacuum Long-Wavelength Crystallography on Beamline I23 at Diamond Light Source
10:32

Sample Preparation and Transfer Protocol for In-Vacuum Long-Wavelength Crystallography on Beamline I23 at Diamond Light Source

Published on: April 23, 2021

3.2K

Related Experiment Videos

Last Updated: Feb 21, 2026

Microcrystallography of Protein Crystals and In Cellulo Diffraction
09:35

Microcrystallography of Protein Crystals and In Cellulo Diffraction

Published on: July 21, 2017

9.6K
Author Spotlight: Advancing Protein Structure Analysis for Drug Development
07:08

Author Spotlight: Advancing Protein Structure Analysis for Drug Development

Published on: March 8, 2024

4.4K
Sample Preparation and Transfer Protocol for In-Vacuum Long-Wavelength Crystallography on Beamline I23 at Diamond Light Source
10:32

Sample Preparation and Transfer Protocol for In-Vacuum Long-Wavelength Crystallography on Beamline I23 at Diamond Light Source

Published on: April 23, 2021

3.2K

Area of Science:

  • Materials Science
  • Crystallography

Background:

  • Understanding the crystal structure landscape is fundamental to materials science.
  • Predicting and analyzing crystal structures informs material properties and applications.

Purpose of the Study:

  • To outline three primary approaches for exploring the crystal structure landscape.
  • To provide an overview of crystal structure prediction, non-ambient crystallography, and charge density analysis.

Main Methods:

  • Crystal structure prediction: Computational methods to determine possible stable crystal structures.
  • Non-ambient crystallography: Studying crystal structures under varying conditions (temperature, pressure).
  • Charge density analysis: Investigating electron distribution within crystals to understand bonding.

Main Results:

  • The study presents a comprehensive overview of these three distinct yet complementary methodologies.
  • Each method offers unique insights into the complexities of crystal structures.

Conclusions:

  • These three approaches collectively enhance our ability to explore and understand the crystal structure landscape.
  • Advancements in these areas are vital for the discovery and design of new materials.