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Long-range magnetic order in the porous metal-organic framework Ni(pyrazine)[Pt(CN)4]
J Alberto Rodríguez-Velamazán1, Olivier Roubeau, Roberta Poloni
1Institut Laue-Langevin, F-38042, Grenoble, France. velamazan@ill.eu.
Abstract:
A combined study involving DFT calculations, neutron scattering, heat capacity and magnetic measurements at very low temperatures demonstrates the long-range magnetic ordering of Ni(pyrazine)[Pt(CN)4] below 1.9 K, describing its antiferromagnetic spin arrangement. This compound belongs to the family of porous coordination polymers M(pyrazine)[Pt(CN)4] (M = divalent metal), renowned for showing interesting combinations of porosity and magnetic properties. The possibility of including long-range magnetic ordering, one of the most pursued functional properties, opens new perspectives for the multifunctionality of this class of compounds.
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