Observations of tropospheric aerosols and NO₂ in Hong Kong over 5years using ground based MAX-DOAS

In this paper, we present long term observations of atmospheric aerosols and nitrogen dioxide (NO₂) in Hong Kong using a Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) instrument. Ground based MAX-DOAS measurements were performed over 5years from December 2010 to November 2015. Vertical distribution profiles of aerosols and NO₂ were derived from MAX-DOAS O₄ and NO₂ observations by applying the optimal estimation method. Retrieved MAX-DOAS measurements of aerosols and NO₂ show good agreement with sun photometer observation of aerosol optical depths (AODs) and long path DOAS measurement of ground level NO₂ mixing ratios. Tropospheric vertical column densities (VCDs) of NO₂ derived from MAX-DOAS measurements are used to validate OMI satellite NO₂ observations. Daily data show reasonably good agreement with each other with Pearson correlation coefficient R=0.7. However, MAX-DOAS NO₂ VCDs are on average higher than OMI observations by a factor of 2. Introducing aerosols in the air mass factor calculation would enhance the OMI VCDs by 7-13%, the remaining discrepancy is mainly due to the differences in spatial coverage between the two instruments. Diurnal variation patterns of aerosols and NO₂ indicated significant contributions from local anthropogenic emissions. Analysis of air mass transport shows that the enhancement of surface aerosols and NO₂ concentrations mainly results from accumulation of local emissions under low wind speed conditions.