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Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes

Javier Fajardo1, Jonas C Peters1

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.

Journal of the American Chemical Society
|October 28, 2017
PubMed
Summary

Ruthenium (Ru) and Osmium (Os) complexes now catalyze nitrogen fixation (N2RR), converting N2 to ammonia (NH3). The Osmium system is most active, yielding over 120 equivalents of NH3, with a hydrazido intermediate proposed.

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