Surface Complexed ZnO Quantum Dot for White Light Emission with Controllable Chromaticity and Color Temperature

We report the formation of blue emitting Zn(MSA)₂ complex on the surface of a yellow emitting ZnO quantum dot (Qdot)-out of a complexation reaction between N-methylsalicylaldimine (MSA) and ZnO Qdot. This led to formation of a highly luminescent, photostable, single-component nanocomposite that emits bright natural white light, with (i) chromaticities of (0.31, 0.38) and (0.31, 0.36), (ii) color rendering indices (CRI) of 74 and 82, and (iii) correlated color temperatures (CCT) of 6505 and 6517 K in their solution and solid phases, respectively. Importantly, the control over the chromaticity and CCT-depending upon the degree of complexation-makes the reported nanocomposite a potential new advanced material in fabricating cost-effective single-component white light emitting devices (WLED) of choice and design in the near future.