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Updated: Feb 18, 2026

Fabrication of Gate-tunable Graphene Devices for Scanning Tunneling Microscopy Studies with Coulomb Impurities
Published on: July 24, 2015
Symmetry Effects on Attenuation Factors in Graphene-Based Molecular Junctions
Qian Zhang1,2, Shuhui Tao1,2, Ruowei Yi1,2
1Department of Chemistry, Xi'an-Jiaotong Liverpool University , 215123 Suzhou, China.
Abstract:
The unique structural and electronic characteristics of graphene make it an attractive contact for fundamental single-molecule electrical studies. With this in mind, we have probed here the electrical conductance of a molecular junction based on α,ω-diaminoalkane chains sandwiched between a gold and a graphene electrode. Using an STM based I(s) method combined with density functional theory-based transport calculations, we demonstrate that the resulting attenuation factor turns out to be much lower when compared to the standard molecular junction between two gold electrodes. This effect is attributed to asymmetric coupling of the molecule through strong chemisorption at the gold electrode and weaker van der Waals contact at graphene. Moreover, this asymmetric coupling induces higher conductance than that in the same hybrid metal-graphene molecular junction using standard thiol anchoring groups.
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