Metastable State during Melting and Solid-Solid Phase Transition of [C_nMim][NO₃] (n = 4-12) Ionic Liquids by...

We simulate the heating process of ionic liquids [C_nMim][NO₃] (n = 4, 6, 8, 10, 12), abbreviated as C_n, by means of molecular dynamics (MD) simulation starting from a manually constructed triclinic crystal structure composed of polar layers containing anions and cationic head groups and nonpolar regions in between containing cationic alkyl side chains. During the heating process starting from 200 K, each system undergoes first a solid-solid phase transition at a lower temperature, and then a melting phase transition at a higher temperature to an isotropic liquid state (C₄, C₆, and C₈) or to a liquid crystal state (C₁₀ and C₁₂). After the solid-solid phase transition, all systems keep the triclinic space symmetry, but have a different set of lattice constants. C₄ has a more significant structural change in the nonpolar regions which narrows the layer spacing, while the layer spacings of other systems change little, which can be qualitatively understood by considering that the contribution of the effective van der Waals interaction in the nonpolar regions (abbreviated as EF1) to free energy becomes stronger with increasing side-chain length, and at the same time the contribution of the effective electrostatic interaction in the polar layers (abbreviated as EF2) to free energy remains almost the same. The melting phase transitions of all systems except C₆ are found to be a two-step process with an intermediate metastable state appeared during the melting from the crystal state to the liquid or liquid crystal state. Because the contribution of EF2 to the free energy is larger than EF1, the metastable state of C₄ has the feature of having higher ordered polar layers and lower ordered side-chain orientation. By contrast, C₈-C₁₂ have the feature of having lower ordered polar layers and higher ordered side-chain orientation, because for these systems, the contribution of EF2 to the free energy is smaller than EF1. No metastable state is found for C₆ because the free-energy contribution of EF1 is balanced with EF2.