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Evidence for Aggregation-Induced Emission from Free Rotation Restriction of Double Bond at Excited State
Jia-Bin Xiong1, Ying-Xue Yuan1, Lian Wang2,3
1Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology , Wuhan 430074, China.
Abstract:
This paper reports that cis-TPE dicycles emit strong fluorescence, while the gem dicycles show almost no emission in solution, demonstrating that the free rotation restriction of the double bond at the excited state is the key factor for AIE effects.
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