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A luminescent Schiff-base heterotrinuclear Zn2Dy single-molecule magnet with an axial crystal field
Ahlem-Linda Boulkedid1, Jérôme Long, Chahrazed Beghidja
1Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université frères Mentouri Constantine, Route Aïn elbey, 25000 Constantine, Algeria.
Abstract:
We report here the synthesis and investigation into the magnetic properties of a luminescent trinuclear Zn2Dy Schiff-base complex that exhibits a zero-field single-molecule magnet behaviour. Magneto-structural correlation confirms that the axial crystal-field is generated by the phenoxide moieties while the characteristic Dy3+-based luminescence is observed.
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