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Updated: Feb 15, 2026

Writing and Low-Temperature Characterization of Oxide Nanostructures
Published on: July 18, 2014
CuWO4 as a photocatalyst for room temperature aerobic benzylamine oxidation
Aaron D Proctor1, Shobhana Panuganti, Bart M Bartlett
1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109-1055, USA. bartmb@umich.edu.
Abstract:
The aerobic photochemical oxidation of benzylamine was carried out on the ternary oxides CuWO4 and BiVO4 as a test proton-coupled-electron-transfer reaction in acetonitrile. Both oxides give the coupled imine product, N-benzylidenebenzylamine, in near quantitative (98-99%) yield, with rate constants of 0.34 h-1 g-1 and 0.70 h-1 g-1 for CuWO4 and BiVO4, respectively.
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