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Updated: Feb 15, 2026

Total Internal Reflection Absorption Spectroscopy TIRAS for the Detection of Solvated Electrons at a Plasma-liquid Interface
Published on: January 24, 2018
Solvated-electron production using cyanocuprates is compatible with the UV-environment on a Hadean-Archaean Earth
Zoe R Todd1, Albert C Fahrenbach, Christopher J Magnani
1Department of Astronomy, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138, USA. zoe.todd@cfa.harvard.edu.
Abstract:
UV-driven photoredox processing of cyanocuprates can generate simple sugars necessary for prebiotic synthesis. We investigate the wavelength dependence of this process from 215 to 295 nm and generally observe faster rates at shorter wavelengths. The most efficient wavelengths are accessible to a range of potential prebiotic atmospheres, supporting the potential role of cyanocuprate photochemistry in prebiotic synthesis on the early Earth.
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