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Published on: August 10, 2017
Intense excimer CPL of pyrenes linked to a quaternaphthyl
Kazuto Takaishi1, Ryosuke Takehana, Tadashi Ema
1Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama, Japan. takaishi@okayama-u.ac.jp ema@cc.okayama-u.ac.jp.
Abstract:
(R,R,R)-Quaternaphthyls possessing eight and six pyrenes (compounds 4 and 3) displayed intense excimer-CPL. The glum values in solution and in the solid state were +0.034-0.037 and +0.0053-0.0056, respectively. The glum values of 3 and 4 were indistinguishable, indicating that the pyrenes of 3 and 4 assumed the same conformation, even in excited states. The intense CPL was caused by conformationally rigid pyrenes arranged via the cumulative steric effects along the quaternaphthyl axis.
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