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Updated: Feb 15, 2026

The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
Published on: September 30, 2014
A stable thiolato-CuI-thiolato triple linkage that bridges two cobalt(iii) centres
Naoyuki Oya1, Mihoko Yamada, Sireenart Surinwong
1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
Abstract:
Treatment of Λ-fac-[Co(d-pen-N,S)3]3- (d-H2pen = d-penicillamine) with Cu+ in water gave a stable CoCu complex, ΛΛ-[Co2Cu3(d-pen)6]3- ([1]3-), having three thiolato-copper(i)-thiolato moieties that bridge two cobalt(iii) centres. Complex [1]3- was isolated as a coordination polymer of Na3[1], which was converted to a complex salt of [Cr(H2O)6][1] by treatment with Cr(NO3)3.
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