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Multiwavelength Raman Spectroscopic Analysis of Superficial Iron-Chromium Oxides Generated Using Laser Irradiation.

Martin Ortiz-Morales1,2, Juan Jose Soto-Bernal1, Claudio Frausto-Reyes2

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|January 31, 2018
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Raman spectroscopy using multiple laser wavelengths effectively characterizes iron-chromium oxides on stainless steel. The excitation wavelength significantly impacts the observed Raman bands and oxide features.

Keywords:
Iron–chromium oxideRaman spectroscopyVis-NIRexcitation wavelengthslaser irradiationvisible–near-infrared

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Area of Science:

  • Materials Science
  • Spectroscopy
  • Surface Science

Background:

  • Laser irradiation of stainless steel generates iron-chromium oxides.
  • Characterizing these oxides is crucial for understanding material properties and performance.
  • Previous studies may not have fully explored the impact of excitation wavelength on Raman spectra of these oxides.

Purpose of the Study:

  • To characterize iron-chromium oxides formed on stainless steel surfaces using multiwavelength Raman spectroscopy.
  • To investigate the influence of different excitation wavelengths on the observed Raman spectra.
  • To identify novel Raman bands and understand resonant excitation conditions.

Main Methods:

  • Raman spectroscopy was performed on austenitic SS304 and ferritic SS430 stainless steel samples.
  • Five excitation wavelengths (455 nm to 830 nm) were utilized.
  • Raman spectra were analyzed to identify characteristic bands and their dependence on excitation wavelength.

Main Results:

  • Four Raman bands were observed, with two previously uncharacterized for iron-chromium oxides.
  • Different excitation wavelengths exhibited distinct resonant conditions, affecting band visibility (e.g., 485 cm⁻¹ band).
  • Spectra profiles varied with excitation wavelength for both film and microsphere oxide features.

Conclusions:

  • The choice of excitation wavelength is critical for accurate Raman characterization of metallic oxides.
  • Multiwavelength Raman analysis reveals complex resonant behaviors in iron-chromium oxides.
  • This study highlights the importance of excitation wavelength selection for comprehensive material analysis.