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Updated: Feb 15, 2026

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
Published on: June 13, 2022
Imido-P(v) trianion supported enantiopure neutral tetrahedral Pd(ii) cages
Prabhakaran Rajasekar1, Swechchha Pandey, Harshad Paithankar
1Department of Chemistry, Indian Institute of Science Education and Research (IISER) Pune, Dr HomiBhabha Road, Pune - 411008, India. boomi@iiserpune.ac.in cjeet@iiserpune.ac.in.
Abstract:
Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantioselective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(ii) cages built from chiral tris(imido)phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, β-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone.
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