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Published on: August 30, 2017
Atomistic evolution during the phase transition on a metastable single NaYF4:Yb,Er upconversion nanoparticle
Min Wook Pin1,2, Eun Jin Park3,4, Suji Choi1,5
1Korea Research Institute of Standard and Science, 267 Gajeong-ro, Yuseong-gu, Daejeon, 34113, Republic of Korea.
Abstract:
The phase evolution of as-prepared NaYF4:Yb,Er upconversion nanoparticles (UCNPs) with a metastable cubic structure is studied based on in situ heating experiments via transmission electron microscopy (TEM). The atomistic behavior on the single NaYF4:Yb,Er UCNP is observed during the phase transition. The formation and evolution of voids on the NaYF4:Yb,Er UCNP appear at a temperature below 420 °C. Small circular voids are transformed at the initial stage to a large, hexagonal-pillar shaped single void. Two different routes to reach the stable α-phase from the metastable cubic structure are identified on a single NaYF4:Yb,Er UCNP. The first is via a stable β-phase and the second is a direct change via a liquid-like phase. The specific orientation relationships, [110]cubic//[11[Formula: see text]0]hexagonal and {002}cubic//{2[Formula: see text]00}hexagonal, between the cubic and hexagonal structures are confirmed. Additionally, a few extra-half planes terminated in the cubic structures are also observed at the cubic/hexagonal interface.
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